全文获取类型
收费全文 | 3148篇 |
免费 | 443篇 |
国内免费 | 549篇 |
专业分类
化学 | 1832篇 |
晶体学 | 25篇 |
力学 | 62篇 |
综合类 | 10篇 |
数学 | 906篇 |
物理学 | 1305篇 |
出版年
2024年 | 5篇 |
2023年 | 130篇 |
2022年 | 102篇 |
2021年 | 135篇 |
2020年 | 152篇 |
2019年 | 114篇 |
2018年 | 134篇 |
2017年 | 127篇 |
2016年 | 151篇 |
2015年 | 150篇 |
2014年 | 240篇 |
2013年 | 326篇 |
2012年 | 335篇 |
2011年 | 355篇 |
2010年 | 239篇 |
2009年 | 303篇 |
2008年 | 184篇 |
2007年 | 196篇 |
2006年 | 152篇 |
2005年 | 101篇 |
2004年 | 66篇 |
2003年 | 50篇 |
2002年 | 39篇 |
2001年 | 52篇 |
2000年 | 46篇 |
1999年 | 53篇 |
1998年 | 60篇 |
1997年 | 38篇 |
1996年 | 14篇 |
1995年 | 18篇 |
1994年 | 8篇 |
1993年 | 14篇 |
1992年 | 17篇 |
1991年 | 11篇 |
1990年 | 9篇 |
1989年 | 3篇 |
1988年 | 4篇 |
1987年 | 1篇 |
1986年 | 4篇 |
1980年 | 1篇 |
1976年 | 1篇 |
排序方式: 共有4140条查询结果,搜索用时 31 毫秒
1.
从头发的结构和组成出发分析头发形状和颜色改变的可能性,剖析烫发、染发的化学原理,阐释先烫发后染发的本质原因,从化学视角辨证地看待烫发、染发的利弊。 相似文献
2.
Hexagonal boron phosphide and boron arsenide van der Waals heterostructure as high-efficiency solar cell 下载免费PDF全文
The rapid development of two-dimensional (2D) materials offers new opportunities for 2D ultra-thin excitonic solar cells (XSCs). The construction of van der Waals heterostructure (vdWH) is a recognised and effective method of integrating the properties of single-layer 2D materials, creating particularly superior performance. Here, the prospects of h-BP/h-BAs vdW heterostructures in 2D excitonic solar cells are assessed. We systematically investigate the electronic properties and optical properties of heterogeneous structures by using the density functional theory (DFT) and first-principles calculations. The results indicate that the heterogeneous structure has good optoelectronic properties, such as a suitable direct bandgap and excellent optical absorption properties. The calculation of the phonon spectrum also confirms the well-defined kinetic stability of the heterstructure. We design the heterogeneous structure as a model for solar cells, and calculate its solar cell power conversion efficiency which reaches up to 16.51% and is higher than the highest efficiency reported in organic solar cells (11.7%). Our work illustrates the potential of h-BP/h-BAs heterostructure as a candidate for high-efficiency 2D excitonic solar cells. 相似文献
3.
4.
《中国化学快报》2019,30(11):1951-1954
Utilization of intermolecular Friedel-Crafts and intramolecular condensation reaction,novel 1,3-di-(pyridine-2-yl)benzene(N,C,N terdentate) skeleton with electro-withdrawing group in 6' position of pyridyl and a cyclization between 6' position of pyridyl and 6 position of benzyl ring were firstly designed and synthesized.The structures of these novel N,C,N terdentate were confirmed by NMR,MS and X-ray single crystalanalyses.The photophysical properties of these compounds were briefly explored. 相似文献
5.
ABSTRACTThis study computes the potential energy curves of the X1Σ+, A1Π, B1Δ, C1Σ+, and D1Π states of AlO+ cation and the transition dipole moments between them. The orders of the rotationless radiative lifetimes are 10–100?μs for the A1Π state, 1–1000?ms for the B1Δ state, 10?ns for the first well and 100?ns for the second well of the C1Σ+ state, and 1?μs for the D1Π state. Emissions of the B1Δ–A1Π and D1Π–C1Σ+ systems are so weak that they are hardly measured via spectroscopy, the emissions of the C1Σ+–X1Σ+, C1Σ+–A1Π, and D1Π–X1Σ+ systems are so strong that they can be detected readily, and emissions of the A1Π–X1Σ+ and D1Π–A1Π systems can be observed through spectroscopy only by a significant effort. There is a strong great similarity between spontaneous emissions of the A1Π–X1Σ+ system of the AlO+ cation and the A2Π–X2Σ+ system of the AlO radical. The emissions of the A2Π–X2Σ+ system of the AlO radical have been measured in outer space Therefore, it is highly possible that the emissions of the A1Π–X1Σ+ system of the AlO+ cation can be detected in the astrophysical media. 相似文献
6.
The Biogeography-Based Optimization algorithm and its variants have been used widely for optimization problems. To get better performance, a novel Biogeography-Based Optimization algorithm with Hybrid migration and global-best Gaussian mutation is proposed in this paper. Firstly, a linearly dynamic random heuristic crossover strategy and an exponentially dynamic random differential mutation one are presented to form a hybrid migration operator, and the former is used to get stronger local search ability and the latter strengthen the global search ability. Secondly, a new global-best Gaussian mutation operator is put forward to balance exploration and exploitation better. Finally, a random opposition learning strategy is merged to avoid getting stuck in local optima. The experiments on the classical benchmark functions and the complexity functions from CEC-2013 and CEC-2017 test sets, and the Wilcoxon, Bonferroni-Holm and Friedman statistical tests are used to evaluate our algorithm. The results show that our algorithm obtains better performance and faster running speed compared with quite a few state-of-the-art competitive algorithms. In addition, experimental results on Minimum Spanning Tree and K-means clustering optimization show that our algorithm can cope with these two problems better than the comparison algorithms. 相似文献
7.
In this paper, we present some necessary and sufficient conditions under which an irreducible polynomial is self-reciprocal (SR) or self-conjugate-reciprocal (SCR). By these characterizations, we obtain some enumeration formulas of SR and SCR irreducible factors of , , over , which are just open questions posed by Boripan et al. (2019). We also count the numbers of Euclidean and Hermitian LCD constacyclic codes and show some well-known results on Euclidean and Hermitian self-dual constacyclic codes in a simple and direct way. 相似文献
8.
《中国化学快报》2020,31(7):1919-1922
A novel BODIPY (boradiazaindacene) dye denoted as BODIPY-DT containing terpyridine unit has been designed and characterized. The dye is found to be selective and visual solvatochromic sensor toward DMF among test organic solvents. The sensing process displays time-controllable, dynamic signal outputs in the emission colors including red, purple, yellow and even white emission colors. It is presented that selective free radical oxidation reaction happens during the recognition process. 相似文献
9.
Dan Xie Huan-Huan Li Yan-Hong Shi Wan-Yue Diao Ru Jiang Prof. Hai-Zhu Sun Prof. Xing-Long Wu Dr. Wenliang Li Dr. Chao-Ying Fan Prof. Jing-Ping Zhang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(4):853-862
The Fe-based transition metal oxides are promising anode candidates for lithium storage considering their high specific capacity, low cost, and environmental compatibility. However, the poor electron/ion conductivity and significant volume stress limit their cycle and rate performances. Furthermore, the phenomena of capacity rise and sudden decay for α-Fe2O3 have appeared in most reports. Here, a uniform micro/nano α-Fe2O3 nanoaggregate conformably enclosed in an ultrathin N-doped carbon network (denoted as M/N-α-Fe2O3@NC) is designed. The M/N porous balls combine the merits of secondary nanoparticles to shorten the Li+ transportation pathways as well as alleviating volume expansion, and primary microballs to stabilize the electrode/electrolyte interface. Furthermore, the ultrathin carbon shell favors fast electron transfer and protects the electrode from electrolyte corrosion. Therefore, the M/N-α-Fe2O3@NC electrode delivers an excellent reversible capacity of 901 mA h g−1 with capacity retention up to 94.0 % after 200 cycles at 0.2 A g−1. Notably, the capacity rise does not happen during cycling. Moreover, the lithium storage mechanism is elucidated by ex situ XRD and HRTEM experiments. It is verified that the reversible phase transformation of α↔γ occurs during the first cycle, whereas only the α-Fe2O3 phase is reversibly transformed during subsequent cycles. This study offers a simple and scalable strategy for the practical application of high-performance Fe2O3 electrodes. 相似文献
10.